Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
3651445
Reference Type
Journal Article
Title
Highly cross-linked thermosetting resin of maleimidobenzoxazine functionalized with benzocyclobutene
Author(s)
Cheng, Y; Qi, T; Jin, Y; Deng, D; Xiao, F
Year
2013
Is Peer Reviewed?
1
Journal
Polymer
ISSN:
0032-3861
Book Title
Polymer
Volume
54
Issue
1
Page Numbers
143-147
DOI
10.1016/j.polymer.2012.11.008
Web of Science Id
WOS:000322356000018
URL
http://www.sciencedirect.com/science/article/pii/S0032386112009366
Exit
Abstract
Abstract: Maleimidobenzoxazine monomer functionalized with benzocyclobutene (BCB) and its cured resin has been successfully prepared. BCB-modified maleimidobenzoxazine monomer (HMI–AB) was synthesized by the reaction of 4-aminobenzocyclobutene (AMBCB), p-hydroxyphenylmaleimide (HMI) and paraformaldehyde in dioxane under reflux. Fourier transform infrared spectroscopy (FTIR), ¹H and ¹³C nuclear magnetic resonance spectroscopy (NMR) were used to characterize the structure of the monomer. The monomer HMI–AB possesses three kinds of polymerizable functional groups of BCB, maleimide and benzoxazine. The polymerization behavior of the monomer is studied by differential scanning calorimetry (DSC) and FTIR. DMA study demonstrates that the cured resin show high storage modulus and high Tg at ca. 350 °C. TGA study shows that the cured resin possess good thermal stability. ds: Internet resource her supplied data e field[29]: 1,4-Dioxane
Keywords
Maleimide; Benzoxazine; Benzocyclobutene
Tags
OPPT REs
•
OPPT_1,4-Dioxane_D. Exposure
Total – title/abstract screening
Supplemental Search
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity