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Citation
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HERO ID
3652555
Reference Type
Journal Article
Title
Fluorescence PET (photo-induced electron transfer) sensor for water based on anthracene-amino acid
Author(s)
Ooyama, Y; Matsugasako, A; Nagano, T; Oka, K; Kushimoto, K; Komaguchi, K; Imae, I; Harima, Y
Year
2011
Is Peer Reviewed?
Yes
Journal
Journal of Photochemistry and Photobiology A: Chemistry
ISSN:
1010-6030
EISSN:
1873-2666
Publisher
Elsevier
Book Title
Journal of Photochemistry & Photobiology, A: Chemistry
Volume
222
Issue
1
Page Numbers
52-55
DOI
10.1016/j.jphotochem.2011.04.035
Web of Science Id
WOS:000295241600008
URL
https://linkinghub.elsevier.com/retrieve/pii/S1010603011001912
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Abstract
Abstract: An anthracene-amino acid system with two carboxyl groups has been designed and synthesized as a new class of fluorescence PET (photo-induced electron transfer) sensor for detection of water in organic SOLVENT*s. An enhancement in fluorescence is observed with increasing water content in 1,4-dioxane, THF, acetonitrile and ethanol, which is attributable to the suppression of PET by the intramolecular proton transfer of the carboxyl proton to the amino group. The detection limit and quantitation limit are, respectively, 0.1 and 0.3wt% for 1,4-dioxane, 0.4 and 1.2wt% for THF, 0.1 and 0.3wt% for acetonitrile and 0.1 and 0.3wt% for ethanol. ds: Internet resource her supplied data e field[29]: 1,4-Dioxane
Keywords
Anthracene-amino acid; Fluorescence; Photo-induced electron transfer; Water
Tags
OPPT REs
•
OPPT_1,4-Dioxane_D. Exposure
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