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3652555 
Journal Article 
Fluorescence PET (photo-induced electron transfer) sensor for water based on anthracene-amino acid 
Ooyama, Y; Matsugasako, A; Nagano, T; Oka, K; Kushimoto, K; Komaguchi, K; Imae, I; Harima, Y 
2011 
Yes 
Journal of Photochemistry and Photobiology A: Chemistry
ISSN: 1010-6030
EISSN: 1873-2666 
Elsevier 
Journal of Photochemistry & Photobiology, A: Chemistry 
222 
52-55 
Abstract: An anthracene-amino acid system with two carboxyl groups has been designed and synthesized as a new class of fluorescence PET (photo-induced electron transfer) sensor for detection of water in organic SOLVENT*s. An enhancement in fluorescence is observed with increasing water content in 1,4-dioxane, THF, acetonitrile and ethanol, which is attributable to the suppression of PET by the intramolecular proton transfer of the carboxyl proton to the amino group. The detection limit and quantitation limit are, respectively, 0.1 and 0.3wt% for 1,4-dioxane, 0.4 and 1.2wt% for THF, 0.1 and 0.3wt% for acetonitrile and 0.1 and 0.3wt% for ethanol. ds: Internet resource her supplied data e field[29]: 1,4-Dioxane 
Anthracene-amino acid; Fluorescence; Photo-induced electron transfer; Water 
OPPT REs
• OPPT_1,4-Dioxane_D. Exposure
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