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3697528 
Journal Article 
Catalytic Oxidation of N-Phosphonomethyliminodiacetic Acid to Synthesize N-Phosphonomethylylycine 
Xu, Y; Dai, S; Chen, T 
2013 
Yes 
Asian Journal of Chemistry
ISSN: 0970-7077
EISSN: 0975-427X 
25 
18 
10597-10598 
A process of preparing the herbicide N-phosphonomethylylycine by oxidizing N-phosphonomethyliminodiacetic acid was investigated. The content of N-phosphonomethylylycine was above 75.04 %. The solid yield was 73.34 % and the total yield was 87.63 % when the reaction was carried out with the mol ratio of the manganese salt catalyst and N-phosphonomethyliminodiacetic acid as 0.04:1 at 80 degrees C under 0.4 MPa for 90 min. 
N-Phosphonomethyliminodiacetic acid; N-Phosphonomethylylycine; Transition metal