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HERO ID
3705273
Reference Type
Journal Article
Title
Effect of Mn and Nb Doped BaTiO3 in the Dielectric Properties in the Ba(Mn1/2Nb1/2)(x)Ti1-xO3
Author(s)
Boujelben, F; Khemakhem, H; Simon, A
Year
2012
Is Peer Reviewed?
Yes
Journal
Journal of Electronic Materials
ISSN:
0361-5235
EISSN:
1543-186X
Volume
41
Issue
8
Page Numbers
2250-2255
DOI
10.1007/s11664-012-2027-4
Web of Science Id
WOS:000305748700032
Abstract
Polycrystalline samples of BaTi1-x (Mn0.5Nb0.5) (x) O-3 with x = 0.025, 0.05, 0.075, 0.1, 0.125, 0.15, and 0.175 have been synthesized by the high-temperature solid-state reaction technique. The effects of cationic substitution of manganese and niobium for titanium at B sites of the BaTiO3 perovskite lattice on symmetry and dielectric properties were investigated. X-ray diffraction at room temperature and dielectric permittivity in the temperature range from 85 K to 500 K and frequency range from 100 Hz to 2 x 10(5) Hz were studied. The evolution from a normal ferroelectric to a relaxor ferroelectric is emphasized. T (C) or T (m) decreases when both manganese and niobium are introduced into the lattice of BaTiO3. High dielectric constant of around 9000 at T (C) = 280 K was found for Ba Ti-0.925(Mn0.5Nb0.5)(0.075)O-3 ceramic. A relaxor ferroelectric with Delta T (m) = 60 K and of about 3500 at 10 kHz with T (m) = 150 K was found for the BaTi0.85(Mn0.5Nb0.5)(0.15)O-3 sample.
Keywords
Ferroelectrics; x-ray diffraction; dielectric response
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