US EPA

3801732 

Journal Article 

Calculation of reaction energies and adiabatic temperatures for waste tank reactions. Waste Tank Safety Program 

Burger, LL 

1993 

18 

50 

Sponsored by Department of Energy, Washington, DC. ual concern has been expressed over potentially hazardous exothermic reactions that might occur in underground Hanford waste tanks. These tanks contain many different oxidizable compounds covering a wide range of concentrations. Several may be in concentrations and quantities great enough to be considered a hazard in that they could undergo rapid and energetic chemical reactions with nitrate and nitrite salts that are present. The tanks also contain many inorganic compounds inert to oxidation. In this report the computed energy that may be released when various organic and inorganic compounds react is computed as a function of the reaction mix composition and the temperature. The enthalpy, or integrated heat capacity, of these compounds and various reaction products is presented as a function of temperature, and the enthalpy of a given mixture can then be equated to the energy release from various reactions to predict the maximum temperature that may be reached. This is estimated for several different compositions. Alternatively, the amounts of various diluents required to prevent the temperature from reaching a critical value can be estimated. 

Ferrocyanides; Nitrates; Nitrites; Radioactive Wastes; Sodium Compounds; Chemical Reactions; Combustion; Flammability; Hanford Reservation; Kinetics; Oxidation; Reaction Intermediates; Temperature Effects; Thermodynamics; Underground Storage; EDB/052002; EDB/400201