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3829663 
Journal Article 
Kinetic study of solvent effects on the hydrolysis of di-2-chloroaniline phosphate in dioxane and dimethyl sulfoxide-water medium 
Choure, N; Bhoite, SA 
2009 
Yes 
Journal of the Indian Chemical Society
ISSN: 0019-4522 
86 
12 
1335-1337 
English 
WOS:000273654100012 
Kinetic study of di-2-chloroaniline phosphate was carried out in dioxane and dimethyl sulfoxide-water mixtures of varying compositions 20-50% (v/v). The rate of reaction increases with increasing proportion of dioxane and dimethyl sulfoxide at 80 and 90 degrees C. The activation parameters (E(a), Delta H(not equal), Delta G(not equal), -Delta S(not equal)) have been evaluated and variations of these parameters have been explained on the basis of solvent-solute interaction, solvent of the transition state of the medium. 
Kinetics; hydrolysis; solvent effects; di-2-chloroaniline phosphate 
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• OPPT_1,4-Dioxane_D. Exposure
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