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HERO ID
4000103
Reference Type
Journal Article
Title
Use of glucose as reductant to recover Co from spent lithium ions batteries
Author(s)
Meng, Q; Zhang, Y; Dong, P
Year
2017
Is Peer Reviewed?
1
Journal
Waste Management
ISSN:
0956-053X
EISSN:
1879-2456
Volume
64
Page Numbers
214-218
Language
English
PMID
28325708
DOI
10.1016/j.wasman.2017.03.017
Web of Science Id
WOS:000403862100023
Abstract
A hydrometallurgical leaching process has been developed for recovery of Co and Li from cathode material (LiCoO2) collected from spent LIBs using a mix solution of glucose and phosphoric acid. The spent LiCoO2 before and after leaching process are analyzed by scanning electron microscopy. A leaching rate of about 98% Co and nearly 100% Li is presented with 1.5mol/L phosphoric acid and 0.02mol/L glucose at 80°C in about 2h. During leaching process, glucose was oxidized into monocarboxylic acid with reduction of Co(III) to Co(II). Co in solution was recovered as Co-oxalate after leaching process. Using glucose as reductant to dissolve LiCoO2 with chelating agent of phosphoric acid is achieved here.
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IRIS
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Cobalt
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