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Citation
Tags
HERO ID
4216310
Reference Type
Journal Article
Title
Separation of hexane isomers in a metal-organic framework with triangular channels
Author(s)
Herm, ZR; Wiers, BM; Mason, JA; van Baten, JM; Hudson, MR; Zajdel, P; Brown, CM; Masciocchi, N; Krishna, R; Long, JR
Year
2013
Is Peer Reviewed?
1
Journal
Science
ISSN:
0036-8075
EISSN:
1095-9203
Publisher
American Association for the Advancement of Science
Volume
340
Issue
6135
Page Numbers
960-964
Language
English
PMID
23704568
DOI
10.1126/science.1234071
Web of Science Id
WOS:000319344100042
Abstract
Metal-organic frameworks can offer pore geometries that are not available in zeolites or other porous media, facilitating distinct types of shape-based molecular separations. Here, we report Fe2(BDP)3 (BDP(2-) = 1,4-benzenedipyrazolate), a highly stable framework with triangular channels that effect the separation of hexane isomers according to the degree of branching. Consistent with the varying abilities of the isomers to wedge along the triangular corners of the structure, adsorption isotherms and calculated isosteric heats indicate an adsorption selectivity order of n-hexane > 2-methylpentane > 3-methylpentane > 2,3-dimethylbutane ≈ 2,2-dimethylbutane. A breakthrough experiment performed at 160°C with an equimolar mixture of all five molecules confirms that the dibranched isomers elute first from a bed packed with Fe2(BDP)3, followed by the monobranched isomers and finally linear n-hexane. Configurational-bias Monte Carlo simulations confirm the origins of the molecular separation.
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