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HERO ID
4260502
Reference Type
Journal Article
Title
Homogeneous Catalysis by Manganese-Based Pincer Complexes
Author(s)
Garbe, M; Junge, K; Beller, M
Year
2017
Is Peer Reviewed?
Yes
Journal
European Journal of Organic Chemistry
ISSN:
1434-193X
EISSN:
1099-0690
Issue
30
Page Numbers
4344-4362
DOI
10.1002/ejoc.201700376
Web of Science Id
WOS:000407822200002
Abstract
Base-metal catalysis, especially with non-noble-metal pincer-type catalysts, is increasingly used in organic synthesis and thus becoming more and more important for organometallic chemistry. After ruthenium-, iridium- and iron-based pincer-type complexes became established as state-of-the-art catalysts for (de)hydrogenation reactions in the past decade, manganese complexes have most recently been successfully applied in related transformations. Specifically, this microreview covers their recent progress in (de)hydrogenation and transfer (de)hydrogenation as well as in C-C and C-X bond-forming reactions.
Keywords
Earth-abundant metals; Manganese; Pincer complex; Dehydrogenation; Hydrogenation; Transfer hydrogenation; Bond formation
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