US EPA

4266824 

Journal Article 

Evaluation of guar gum-based biopolymers as binders for lithium-ion batteries electrodes 

Carvalho, DV; Loeffler, N; Hekmatfar, M; Moretti, A; Kim, GukTae; Passerini, S 

2018 

Yes 

Electrochimica Acta
ISSN: 0013-4686 

265 

89-97 

10.1016/j.electacta.2018.01.083 

WOS:000425751600011 

Herein we report the investigation on the use of guar gum and two of its derivatives as LIB positive electrodes binders. These polymers are electrochemically stable within the operating voltage of LIBs (0.01-5 V vs Li/Li+) and do not show evidence of thermal decomposition up to 200 degrees C. The electrochemical performance of lithium nickel manganese cobalt oxide (NMC) electrodes made using guar gum is excellent as indicated, for instance, by the delivered capacity of 100 mAh g(-1) upon 5C rate cycling. Xray Photoelectron Spectroscopy (XPS) measurements of pristine electrodes reveal as the binder layer surrounding the active material particles is thin, resulting in the above-mentioned electrochemical performance. Full lithium-ion cells, utilizing guar gum on both positive and negative electrodes, display a stable discharge capacity of similar to 110 mAh g(-1) (based on cathode active material) with high coulombic efficiencies. Post-mortem investigation by XPS of cycled graphite electrodes from full lithium-ion cells revealed the formation of a thin solid electrolyte interface (SEI). (c) 2018 Elsevier Ltd. All rights reserved. 

Binder; Guar gum; Aqueous process; Lithium-ion battery; Post-mortem analysis