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4267095 
Journal Article 
Silver-Catalyzed Oxidative C(sp3)-P Bond Formation through C-C and P-H Bond Cleavage 
Li, L; Huang, W; Chen, L; Dong, J; Ma, X; Peng, Y 
2017 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
56 
35 
10539-10544 
English 
28654187 
WOS:000407812500047 
The silver-catalyzed oxidative C(sp3)-H/P-H cross-coupling of 1,3-dicarbonyl compounds with H-phosphonates, followed by a chemo- and regioselective C(sp3)-C(CO) bond-cleavage step, provided heavily functionalized β-ketophosphonates. This novel method based on a readily available reaction system exhibits wide scope, high functional-group tolerance, and exclusive selectivity.