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4268103 
Journal Article 
Graphene-Based Flexible Supercapacitors: Pulse-Electropolymerization of Polypyrrole on Free-Standing Graphene Films 
Davies, A; Audette, P; Farrow, B; Hassan, F; Chen, Z; Choi, JaY; Yu, A 
2011 
Yes 
Journal of Physical Chemistry C
ISSN: 1932-7447
EISSN: 1932-7455 
115 
35 
17612-17620 
WOS:000294386000048 
A simple method has been implemented to create flexible, uniform graphene-polypyrrole composite films using a pulsed electropolymerization technique for supercapacitor electrodes. Applying the pseudocapacitive contribution of conformal redox-active polypyrrole to graphene supercapacitor electrodes results in high performance while still maintaining the inherent flexibility of graphene films. Specific capacitances as high as 237 F/g were obtained for a moderate total deposition time of only 120 s, which is approximately four times higher than the blank scaffold, graphene films. This flexible supercapacitor film exhibited very high energy and power densities with values of similar to 33 Wh/kg and similar to 1184 W/kg, respectively, at a scan rate of 0.01 V/s. This increase was attributed to the favorable nucleation of new polymer chains at defects on the graphene surface, which become less favorable as defect sites are occupied by existing polymer nanoparticles.