Synthesis, Crystal Structure and Theoretical Calculations of a Manganese(II) Coordination Polymer Assembled by 2,5-Thiophenedicarboxylic Acid and 3-(2-Pyridyl)pyrazole Ligands
A new Mn(II) complex, [ Mn-0.5(tdc)(0.5)(L)](2n) (1, H(2)tdc = 2,5-thiophenedicarboxylic acid, L = 3-(2-pyridyl) pyrazole), has been successfully synthesized under hydrothermal conditions. Its structure has been determined by single-crystal X-ray diffraction analysis, elemental analyses, IR, TG and UV spectrum. Single-crystal X-ray diffraction analysis reveals that complex 1 belongs to the orthorhombic system, space group Pnna with a = 11.5184(6), b = 16.8399(8), c = 11.7249(5) angstrom, V = 2274.26(19) angstrom(3), Z = 4, D-c = 1.505 g/cm(3), mu = 0.715 mm(-1), M-r = 515.41, F(000) = 1052, the final R = 0.0336 and wR = 0.0802 with I > 2 sigma(I). It exhibits a one-dimensional zigzag-chain structure, which was stabilized through intermolecular C-H center dot center dot center dot O and intramolecular N-H center dot center dot center dot O hydrogen bonding interactions. Moreover, we analyzed Natural Bond Orbital (NBO) by using the PBE0/LANL2DZ method built in Gaussian 09 Program. The calculation results showed obvious covalent interaction between the coordinated atoms and Mn(II) ion.