Synthesis and characterization of a novel schiff base of 1,2-diaminopropane with substituted salicyaldehyde and its transition metal complexes: Single crystal structures and biological activities | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

4269755

Reference Type

Journal Article

Title

Synthesis and characterization of a novel schiff base of 1,2-diaminopropane with substituted salicyaldehyde and its transition metal complexes: Single crystal structures and biological activities

Author(s)

Tadavi, SK; Yadav, AA; Bendre, RS

Year

2018

Is Peer Reviewed?

Yes

Journal

Journal of Molecular Structure
ISSN: 0022-2860
EISSN: 1872-8014

Volume

1152

Page Numbers

223-231

DOI

10.1016/j.molstruc.2017.09.112

Web of Science Id

WOS:000415774400024

Abstract

A novel schiff base H2L derived from simple condensation of 2-hydroxy-6-isopropyl-3-methyl benzaldehyde and 1,2-diaminopropane in 2:1 M ratio and its [MnL], [CoL] and [NiL]2 complexes have been prepared and characterized by spectroscopic technique, elemental analysis, SEM-EDX analysis, and cyclic voltammetry. Additionally, single crystal X-ray diffraction technique has been applied to the schiff base ligand H2L and its nickel complex. The structure of nickel complex exhibited dimeric form with formula [NiL]2 with distorted square planar geometry around each nickel center. Furthermore, all the synthesized compounds were screened for their antimicrobial and antioxidant and DNA cleavage activities. (c) 2017 Published by Elsevier B.V.

Keywords

Schiff base; Metal complexes; Cyclic voltammetry; Antimicrobial; Antioxidant activities