Liquid-Liquid Equilibrium Data for the Ternary Systems of Water, Isopropyl Alcohol, and Selected Entrainers | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

4275283

Reference Type

Journal Article

Title

Liquid-Liquid Equilibrium Data for the Ternary Systems of Water, Isopropyl Alcohol, and Selected Entrainers

Author(s)

Choi, HC; Shin, J; Qasim, F; Park, S

Year

2016

Is Peer Reviewed?

Yes

Journal

Journal of Chemical and Engineering Data
ISSN: 0021-9568
EISSN: 1520-5134

Publisher

American Chemical Society

Volume

Issue

Page Numbers

1403-1411

Language

English

DOI

10.1021/acs.jced.5b00542

Web of Science Id

WOS:000374430900006

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84965076059&doi=10.1021%2facs.jced.5b00542&partnerID=40&md5=7818c85e5e959f60af25414528ec260a
Exit

Abstract

In this study, a substitutive entrairier is found for the azeotropic process of water and isopropyl alcohol (IPA). Liquid-liquid equilibrium (LLE) data are measured for the ternary systems of water-IPA-benzene, water-IPA-cyclohexane, and water IPA-hexane at three different temperature values: 303, 313, and 323 K. The liquid-liquid equilibrium data are developed via an experimental setup equipped with equilibrium cell, magnetic stirrer, and gas chromatography units. Equilibrium compositions for the water-IPA system are found by using three different entrainers: benzene, cyclohexane, and hexane. Parameters calculated by nonrandom two-liquid (NRTL) and universal quasichemical (UNIQUAC) thermodynamic models are compared with the data obtained by experiments, and the comparison shows a good correlation between thermodynamic models and the experimental data.