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4278163 
Journal Article 
A Novel Zn(II) Complex with 4-Connected umc Topology: Synthesis, Crystal Structure and Luminescent Property 
Zhang Zi-You; Xiao Li; Chen Shui-Sheng; Qiao Rui; Yang Song 
2017 
Yes 
Chinese Journal of Structural Chemistry
ISSN: 0254-5861 
36 
5 
819-824 
WOS:000403898700014 
A novel complex, [Zn(L)](2).H2O (1, H2L = 4-aminophthalic acid), has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and PXRD. Complex 1 crystallizes in monoclinic, space group C2/c with a = 12.4267(6), b = 7.7482(3), c = 18.6983(8) angstrom, beta= 110.437(3)degrees, V = 1687.04(13) angstrom(3), Z = 4, C16H12N2O9Zn2, M-r = 507.06, D-c = 1.996 g/cm(3), mu = 2.903 mm(-1), S = 0.989, F(000) = 1016, the final R = 0.0304 and wR = 0.0720 for 12618 observed reflections (I > 2 sigma(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework with 4-connected umc topology. Moreover, the thermogravimetric (TG) analysis and photoluminescent property of 1 were also discussed. 
Zn(II) compound; topology; 3D framework; luminescence