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4281107 
Journal Article 
Synthesis, Characterization, and Photoluminescent Property of a New Cd(II) Coordination Polymer With a (3,5)-Connected Topology 
Yao, P 
2015 
1 
Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
ISSN: 1553-3174 
45 
12 
1875-1878 
WOS:000359163600020 
A new Cd (II) coordination polymer with 2-(4-carboxyphenoxy)benzoic acid (H(2)oba) and 1,3,5-tris(1-imidazolyl)benzene (tib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and elemental analysis. The compound, [Cd(oba)(tib)center dot H2O](n), is orthorhombic, space group Pbca with a = 16.791(2), b = 17.850(2), c = 19.340(2) angstrom, beta = 90 degrees, V = 5580.6(9) angstrom(3), Z = 8, M-r = 662.93, D-c = 1.578 g/cm(3), F(000) = 2672, and mu = 0.837 cm(-1). The final refinement gave R = 0.0263 and wR = 0.0629 for 5094 reflections with I > 2 sigma(I). X-ray diffraction analysis reveals that the title compound [Cd(oba)(tib)center dot H2O](n) displays a (3,5)-connected topology with Schlafli symbol (4.6.8)(4.6(4).8(5)). 
luminescent property; Cd(II); crystal structure