(Diacetoxyiodo) benzene-Mediated Oxygenation of Benzylic C(sp(3))-H Bonds with N-Hydroxyamides at Room Temperature | Health & Environmental Research Online (HERO)

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HERO ID

4284952

Reference Type

Journal Article

Title

(Diacetoxyiodo) benzene-Mediated Oxygenation of Benzylic C(sp(3))-H Bonds with N-Hydroxyamides at Room Temperature

Author(s)

Qian, PC; Liu, Yu; Song, R; Hu, M; Yang, XuH; Xiang, J; Li, J

Year

2015

Is Peer Reviewed?

Yes

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X
EISSN: 1099-0690

Volume

2015

Issue

Page Numbers

1680-1684

Language

English

DOI

10.1002/ejoc.201403616

Web of Science Id

WOS:000351054500006

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85027956580&doi=10.1002%2fejoc.201403616&partnerID=40&md5=af014875ee1dba9ace1aee24659f0d5f
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Abstract

A new, metal-free method for the formation of C(sp(3))-O bonds was established by PhI(OAc)(2)-mediated oxygenation of benzylic C(sp(3))-H bonds with N-hydroxyamides at room temperature, in which the C(sp(3))-H oxidation is activated by a polyflurophenylamide group.

Keywords

Oxidation; N-Hydroxyamides; Cross-coupling; Acetamides; Synthetic methods