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4284977 
Journal Article 
Preparation of polymer-derived graphene-like carbon-silicon carbide nanocomposites as electromagnetic interference shielding material for high temperature applications 
Li, Z; Wang, Y 
2017 
Yes 
Journal of Alloys and Compounds
ISSN: 0925-8388 
709 
313-321 
WOS:000401042300039 
In this study, we used divinyl benzene (DVB) to modify a polycarbosilane precursor via chemical modification in order to fabricate homogenous graphene-like carbon-silicon carbide (C-SiC) nano composites. The electromagnetic interference shielding effectiveness (EMI SE) of the composites was tested over the temperature range from room temperature (RT) to 600 degrees C in air. With increasing DVB content, the conductivity increased due to the lower degree of defects and the better connectivity of the carbon phase, whereas both the oxidation resistance and the EMI SE of the nanocomposites decreased. The results suggest that the degree of defects has a much stronger influence on the EMI SE than the conductivity. Possessing the highest degree of defects and best oxidation resistance, the C-SiC nano composites with a carbon mass percentage of 7.6 wt% showed the highest EMI SE both at RT and 600 degrees C, indicating that they are a promising candidate for an application as shielding material at high temperatures in air. (C) 2017 Elsevier B.V. All rights reserved. 
C-SiC nanocomposites; Chemical modification; Degree of defects; Conductivity; Electromagnetic interference shielding effectiveness