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HERO ID
4372892
Reference Type
Journal Article
Title
Synthesis and properties of photocross-linked polymers of epoxidized linseed oil with different reactive diluents
Author(s)
Remeikyte, A; Ostrauskaite, J; Grazuleviciene, V
Year
2013
Is Peer Reviewed?
Yes
Journal
Journal of Applied Polymer Science
ISSN:
0021-8995
EISSN:
1097-4628
Volume
129
Issue
3
Page Numbers
1290-1298
DOI
10.1002/app.38816
Web of Science Id
WOS:000318504500043
Abstract
Cross-linked polymers were obtained by photopolymerization of epoxidized linseed oil with different reactive diluents (3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, 1,4-cyclohexane dimethanol diglycidyl ether, bisphenol A diglycidyl ether, trimethylolpropane triglycidyl ether, and bis[4-(glycidyloxy)phenyl]methane) using the mixture of triarylsulfonium hexafluoroantimonates as photoinitiator. The kinetic of photocross-linking reactions of compositions with different concentrations of reactive diluents was investigated. The 69%91% conversion of epoxy groups of the compositions containing reactive diluents was reached. The mechanical properties, thermal stability, and swelling in polar and nonpolar solvents of the photocross-linked polymers were studied. (c) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
Keywords
biomaterials; photopolymerization; crosslinking; kinetics; mechanical properties
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