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HERO ID
4422989
Reference Type
Journal Article
Title
Towards a broadband chirped pulse Fourier transform microwave spectrometer
Author(s)
Mani, D; Bhat, VT; Vinoy, KJ; Arunan, E
Year
2012
Is Peer Reviewed?
Yes
Journal
Indian Journal of Physics and Proceedings of the Indian Association for the Cultivation of Science
ISSN:
0973-1458
Volume
86
Issue
3
Page Numbers
225-235
DOI
10.1007/s12648-012-0043-0
Web of Science Id
WOS:000303541500011
Abstract
This article gives a brief review of microwave spectroscopy and the experimental techniques used for obtaining microwave spectrum of molecules and complexes since 1950s. It presents a brief summary of the pulsed nozzle Fourier transform microwave (PNFTMW) spectrometer, fabricated in our laboratory, and discusses some of the important results obtained using the spectrometer. The most significant among the results from this spectrometer is the direct structural determination of weakly bound complexes involving H2O/H2S. These have challenged the conventional wisdom on hydrogen bonding leading us to propose a modern definition for the same through IUPAC. The limitations of the PNFTMW spectrometer and the need for the new chirped pulse Fourier transform microwave spectrometer are discussed as well. Moreover, preliminary results from our laboratory on generating a 1 A mu s chirped pulse of 1 GHz bandwidth are given.
Keywords
Rotational spectroscopy; Supersonic beams; Chirp-pulse; Fourier-transform microwave spectrometer
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