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4576547 
Journal Article 
Polymerization of 5-alkyl delta-lactones catalyzed by diphenyl phosphate and their sequential organocatalytic polymerization with monosubstituted epoxides 
Zhao, J; Hadjichristidis, N 
2015 
6 
14 
2659-2668 
WOS:000351720100007 
Organocatalytic ring-opening polymerization (ROP) reactions of three renewable 5-alkyl delta-lactones, namely delta-hexalactone (HL), delta-nonalactone (NL) and delta-decalactone (DL), using diphenyl phosphate (DPP) were investigated. Room temperature, together with a relatively high monomer concentration (= 3 M), was demonstrated to be suitable for achieving a living ROP behavior, a high conversion of the lactone, a controlled molecular weight and a low dispersity of the polyester. HL, containing a 5-methyl substituent, showed a much higher reactivity (polymerization rate) and a slightly higher equilibrium conversion than the compounds with longer alkyl substituents (NL and DL). The effectiveness of DPP-catalyzed ROP of 5-alkyl delta-lactones facilitated the one-pot performance following the t-BuP4-promoted ROP of monosubstituted epoxides. It has been shown in an earlier study that substituted polyethers acted as "slow initiators" for non-substituted lactones. However, efficient initiations were observed in the present study as substituted lactones were polymerized from the substituted polyethers. Therefore, this reinforces the previously developed " catalyst switch" strategy, making it a more versatile tool for the synthesis of welldefined polyether-polyester block copolymers from a large variety of epoxide and lactone monomers.