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HERO ID
4657397
Reference Type
Journal Article
Title
A Stereoconvergent Cyclopropanation Reaction of Styrenes
Author(s)
Del Hoyo, AM; Herraiz, AG; Suero, MG
Year
2017
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
56
Issue
6
Page Numbers
1610-1613
Language
English
PMID
27981721
DOI
10.1002/anie.201610924
Web of Science Id
WOS:000394998300030
URL
https://www.proquest.com/docview/1914439974?accountid=171501&bdid=65299&_bd=BTbOCijXhLgKcFpKHeEU6GrQYt4%3D
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Abstract
The first stereoconvergent cyclopropanation reaction by means of photoredox catalysis using diiodomethane as the methylene source is described. This transformation exhibits broad functional group tolerance and it is characterized by an excellent stereocontrol en route to trans-cyclopropanes regardless of whether E- or Z-styrene substrates were utilized.
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