Pd(acac)(MeCN)(2)]BF4: air-tolerant, activator-free catalyst for alkene dimerization and polymerization | Health & Environmental Research Online (HERO)

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HERO ID

4665451

Reference Type

Journal Article

Title

Pd(acac)(MeCN)(2)]BF4: air-tolerant, activator-free catalyst for alkene dimerization and polymerization

Author(s)

Suslov, DS; Bykov, MV; Abramov, PA; Pahomova, MV; Ushakov, IA; Voronov, VK; Tkach, VS

Year

2015

Is Peer Reviewed?

Journal

RSC Advances
EISSN: 2046-2069

Volume

Issue

126

Page Numbers

104467-104471

Language

English

DOI

10.1039/c5ra24591e

Web of Science Id

WOS:000366433700085

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84950111708&doi=10.1039%2fc5ra24591e&partnerID=40&md5=7574ed14108b7182afb16a629678ac91
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Abstract

[Pd(acac)(MeCN)(2)]BF4 has been observed to catalyze selective substituted styrene dimerization and addition norbornene polymerization. Theoretical calculations based on BP86 density functional theory have been carried out to clarify the precatalyst activation mechanism.