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HERO ID
4690569
Reference Type
Journal Article
Title
Removal of Heavy Metals in Storm Water Runoff Using Porous Vermiculite Expanded by Microwave Preparation
Author(s)
Lee, T
Year
2012
Is Peer Reviewed?
1
Journal
Water, Air, and Soil Pollution
ISSN:
0049-6979
EISSN:
1573-2932
Volume
223
Issue
6
Page Numbers
3399-3408
DOI
10.1007/s11270-012-1119-3
Web of Science Id
WOS:000304926200047
Abstract
The main objective of this study was to examine the effectiveness of vermiculite for removing heavy metals from water. Vermiculite components were analyzed by X-ray fluorescence, and the concentrations of metal ions were measured by inductively coupled plasma spectrometry. Serial batch kinetic tests and batch sorption tests were conducted to determine the removal characteristics for heavy metals in aqueous solutions. Solution pH values of tests with the inflated vermiculites generally increased and then stabilized. Equilibrium pH was generally established within 5 h. Removal rates of inflated vermiculite were tested at the initial concentration of 3 mg/L. At equilibrium concentrations, except for chromium (36.23%), most heavy metals were effectively removed (96.08-98.54%). Finally, sorption data were correlated with both Langmuir and Freundlich isotherms. For each metal, the Q (max) obtained using the Langmuir isotherm was as follows: lead, 725.4 mg kg(-1); cadmium, 568.8 mg kg(-1); zinc, 540.2 mg kg(-1); copper, 457.2 mg kg(-1); and chromium, 0.9 mg kg(-1). The study results indicate that inflated vermiculite has outstanding removal rates and therefore can be used as an adsorbent for various heavy metals.
Keywords
Heavy metals; Adsorption; Vermiculite; Microwave; Batch sorption tests
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