Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1,3-butadiene in supercritical carbon dioxide | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

4699118

Reference Type

Journal Article

Title

Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1,3-butadiene in supercritical carbon dioxide

Author(s)

Meng, F; Feng, X; Wang, W; Bao, M

Year

2017

Is Peer Reviewed?

Journal

Chinese Chemical Letters
ISSN: 1001-8417
EISSN: 1878-5964

Volume

Issue

Page Numbers

900-904

DOI

10.1016/j.cclet.2016.12.018

Web of Science Id

WOS:000402214400034

URL

http://www.sciencedirect.com/science/article/pii/S1001841716304570
Exit

Abstract

An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed. The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding 5-vinyl-2-norbornene in satisfactory yield with high selectivity. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

Keywords

5-Vinyl-2-norbornene; Diels-Alder reaction; Cyclopentadiene; 1,3-Butadiene; Supercritical carbon dioxide