Health & Environmental Research Online (HERO)


Print Feedback Export to File
4711184 
Journal Article 
STUDY OF THE EFFECT OF POLYMER NETWORK STRUCTURE ON THERMAL AND MECHANICAL PROPERTIES OF CROSSLINKED (METH)ACRYLATES - CIS-HEXAHYDROPHTHALIC ANHYDRIDE DERIVATIVES 
Podgorski, M; Ksiezopolski, J 
2010 
1 
Polimery
ISSN: 0032-2725 
55 
1 
33-40 
WOS:000273367600005 
The novel multifunctional monomers, glycidyl esters of trimethacrylic acid or dimethacrylic-acrylic one were prepared via three-stage synthesis method (Table 1, Fig. 1). Their homopolymers or copolymers with styrene were obtained in photopolymerization processes. Mechanical and thermal properties of the polymerizations products (Fig. 2-5) were evaluated. The degree of conversion of unsaturated bonds was determined (Fig. 6, 7) and dynamic thermal analyses were done (Table 2). Quality evaluation of the degree of structural heterogeneity of polymer networks obtained has been done and the effect of heterogeneity on the product properties was discussed. 
photopolymerization; multimethacrylates; mechanical properties; thermal properties; dynamic mechanical analysis