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HERO ID
4716149
Reference Type
Journal Article
Title
Ni nanoparticles supported on microwave-synthesised saponite for the hydrogenation of styrene oxide
Author(s)
Vicente, I; Salagre, P; Cesteros, Y
Year
2011
Is Peer Reviewed?
Yes
Journal
Applied Clay Science
ISSN:
0169-1317
Volume
53
Issue
2
Page Numbers
212-219
DOI
10.1016/j.clay.2010.12.025
Web of Science Id
WOS:000294374900014
Abstract
Several saponites were synthesised under microwaves, at different preparation conditions, to be used as supports of nickel nanoparticles for the catalytic hydrogenation of styrene oxide to 2-phenylethanol. Ni/saponites obtained by impregnation with the highest nickel content (20 wt.%) or by using saponites synthesised at lower pH (pH = 7) resulted in high activity, high selectivity to 2-phenylethanol, and high resistance to deactivation catalysts. Catalytic results were related to the different NiO-saponite interactions observed by TPR. (C) 2010 Elsevier B.V. All rights reserved.
Keywords
Saponite; Microwaves; Hydrothermal treatment; Nickel nanoparticles; Styrene oxide; 2-phenylethanol
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