US EPA

4747780 

Journal Article 

Precisely Composition Controlled Synthesis of Cu0.5Ni0.5 Alloy with Optimum Catalytic Activity 

Xu Xing-Liang; Li Li-Ping; Zhang Dan; Luo Jia-Jun; Li Guang-She 

2017 

Yes 

Chinese Journal of Structural Chemistry
ISSN: 0254-5861 

36 

12 

2033-2043 

10.14102/j.cnki.0254-5861.2011-1727 

WOS:000419109200010 

Alloys based on non-noble metals could be the next generation of high-performance catalysts for many chemical reactions. However, precisely composition controlled synthesis of non-noble alloys remains a significant challenge. In this work, we report a simple synthesis of Cu-0.Ni-5(0.5) alloys without any component segregation. Its success relies on the use of Cu-Ni oxalate precursors, which are chelated in the proximity by oxalate ligands. One of the attractive features for the oxalate routes of catalyst preparation is that no classical support material is needed. The actual component ratios of the obtained Cu0.5Ni0.5 alloy are consistent with the initial ratio. Cu0.5Ni0.5 alloy shows a higher catalytic activity than pure Cu and Ni catalysts in the reduction of p-nitrophenol (4-NP) to p-aminophenol (4-AP) by sodium borohydride (NaBH4) in an aqueous solution, and the performance depends strongly on the strong interaction between Cu and Ni. The findings reported here are highly helpful to understand the relationship between the synergistic effects in alloys and their catalytic performance, and therefore could provide appropriate strategies to obtain desirable catalysts with improved activity in various catalytic applications. 

catalytic reduction; CuNi bimetallic alloy; p-nitrophenol; NaBH4