Two threefold interpenetrated metal-organic frameworks (Co-II, Ni-II) with (6(5).8) topology constructed from biphenyl-3,4-dicarboxylic acid | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

4761964

Reference Type

Journal Article

Title

Two threefold interpenetrated metal-organic frameworks (Co-II, Ni-II) with (6(5).8) topology constructed from biphenyl-3,4-dicarboxylic acid

Author(s)

Sun, Z; Ding, Y; Tian, L; Zhang, X

Year

2013

Is Peer Reviewed?

Yes

Journal

Journal of Coordination Chemistry
ISSN: 0095-8972
EISSN: 1029-0389

Volume

Issue

Page Numbers

763-771

DOI

10.1080/00958972.2013.767895

Web of Science Id

WOS:000320914400003

Abstract

[Co(bmib)(bpda)]center dot H2O (1) and [Ni(bmib)(bpda)] (2) (H(2)bpda=biphenyl-3,4-dicarboxylic acid; bmib=4,4-bis(2-methylimidazol-1-ylmethyl)benzene) were synthesized under hydrothermal conditions. The structures have been determined by single-crystal X-ray diffraction analyzes and further characterized by elemental analyzes, IR, PXRD, and TGA. Compounds 1 and 2 possess a threefold interpenetrated (6(5).8) architecture that incorporates left- and right-handed helical chains. The difference of angles between the coordination spacers in 1 and 2 causes a large difference along the c-axis.

Keywords

Biphenyl-3; 4-dicarboxylic acid; 4; 4-bis(2-methylimidazol-1-ylmethyl)benzene; Nickel(II); Cobalt(II); Helical