Nickel-Molybdenum Sulfide Naphthalene Hydrogenation Catalysts Synthesized by the In Situ Decomposition of Oil-Soluble Precursors | Health & Environmental Research Online (HERO)

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Citation
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HERO ID

4832473

Reference Type

Journal Article

Title

Nickel-Molybdenum Sulfide Naphthalene Hydrogenation Catalysts Synthesized by the In Situ Decomposition of Oil-Soluble Precursors

Author(s)

Sizova, IA; Maksimov, ABL

Year

2017

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Journal

Petroleum Chemistry
ISSN: 0965-5441
EISSN: 1531-8532

Volume

Issue

Page Numbers

595-599

Language

English

DOI

10.1134/S096554411707009X

Web of Science Id

WOS:000405491000006

URL

http://://WOS:000405491000006
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Abstract

Nickel-molybdenum sulfide catalysts for the hydrogenation of aromatic hydrocarbons have been prepared by the in situ decomposition of oil-soluble precursors Mo(CO)(6) and Ni(C7H15COO)(2) in a hydrocarbon feedstock and characterized by HRTEM and XPS. The resulting Ni-Mo sulfide material exhibits high catalytic activity in the naphthalene hydrogenation reaction. An optimum Mo/Ni ratio of 1/2 has been selected.

Keywords

molybdenum hexacarbonyl; unsupported catalysts; nickel-molybdenum sulfide catalyst; hydrogenation of aromatic hydrocarbons