US EPA

4833277 

Journal Article 

Ordered Mesoporous Crystalline Mo-Doped WO2 Materials with High Tap Density as Anode Material for Lithium Ion Batteries 

Chen, F; Wang, Jun; Huang, L; Bao, H; Shi, Y 

2016 

Yes 

Chemistry of Materials
ISSN: 0897-4756
EISSN: 1520-5002 

28 

2 

608-617 

10.1021/acs.chemmater.5b04294 

WOS:000368949900027 

Highly ordered mesoporous crystalline Mo-doped WO2 (MoxW1-xO2: 1 > x > 0.08) materials with different molybdenum contents were synthesized via a nano casting strategy using mesoporous silica KIT-6 as a hard template. The presence of molybdenum significantly increased the rate of reduction of tungsten trioxide to tungsten dioxide using hydrogen gas as the reducing agent, and it also prevented the dioxide product from being further reduced to zerovalent metal tungsten. This molybdenum doping strategy provides a new solution for the synthesis of WO2-based materials with well-defined nanostructures. The obtained mesoporous Mo(0.14)W(0.86)O2 material possessed a metallic conductivity (0.8 Omega cm, 300 K) and a high tap density of 3.6 g cm(-3). This material exhibits a high and reversible lithium storage capacity of 635 mAh g(-1) and is stable up to at least 70 cycles without noticeable fading.