US EPA

4838857 

Journal Article 

The effect of molybdenum on optical properties of ZnO nanoparticles in Ultraviolet-Visible region 

Zak, AK; Ghanbari, A; Shekoftehnarm, T 

2017 

Yes 

Advanced Powder Technology
ISSN: 0921-8831
EISSN: 1568-5527 

28 

11 

2980-2986 

10.1016/j.apt.2017.09.006 

WOS:000416051400020 

Zn1-xMoxO (x = 0.0, 0.01, 0.03, and 0.05) nanoparticles (NPs) are synthesized by using gelatin, via the sol-gel method. A calcination temperature of 600 degrees C is maintained for 2 h. The influence of molybdenum concentration on the structural and optical properties of these NPs is demonstrated. Synthesized NPs are characterized using X-ray diffraction (XRD), UV-vis spectroscopy, and transmission electron microscopy (TEM). XRD patterns reveal the crystallite nature of samples that exist in the hexagonal wurtzite phase. TEM images manifest the existence of nearly spherically-shaped NPs. The UV-vis spectroscopy results showed that the absorption edge of ZnO nanoparticles is red-shifted by adding molybdenum. Finally, the optical parameters of the refractive index and permittivity of the synthesized samples were calculated using Kramers-Kronig relations using the UV-vis spectra. (C) 2017 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved. 

ZnO; Optical properties; Zinc oxide; Molybdenum