Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
4839066
Reference Type
Journal Article
Title
A Family of Homo- and Heteroscorpionate Ligands: Applications to Bioinorganic Chemistry
Author(s)
Carrano, CJ
Year
2016
Is Peer Reviewed?
Yes
Journal
European Journal of Inorganic Chemistry
ISSN:
1434-1948
EISSN:
1099-0682
Issue
15-16
Page Numbers
2377-2390
DOI
10.1002/ejic.201501476
Web of Science Id
WOS:000378724700015
Abstract
In this brief review we focus on a few examples of how a family of homo- and heteroscorpionate ligands allow us to examine how changes in reactivity, structure, or physical/chemical properties around biologically interesting N2X coordinated metal centers vary as a function of donor atom, charge, hydrophobicity, hydrogen bonding, etc., in a way previously unavailable. Such a family of ligands is the bioinorganic chemists answer to site-directed mutagenesis. Here we focus on two bioinorganic examples i.e. models for molybdoenzymes and zinc metalloproteins.
Keywords
Bioinorganic chemistry; Metalloenzyme mimics; Scorpionate ligands; Heteroscorpionate ligands; Molybdenum; Zinc
Tags
IRIS
•
Molybdenum
Litsearch 2018
WOS
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity