Health & Environmental Research Online (HERO)


Print Feedback Export to File
4839066 
Journal Article 
A Family of Homo- and Heteroscorpionate Ligands: Applications to Bioinorganic Chemistry 
Carrano, CJ 
2016 
Yes 
European Journal of Inorganic Chemistry
ISSN: 1434-1948
EISSN: 1099-0682 
15-16 
2377-2390 
In this brief review we focus on a few examples of how a family of homo- and heteroscorpionate ligands allow us to examine how changes in reactivity, structure, or physical/chemical properties around biologically interesting N2X coordinated metal centers vary as a function of donor atom, charge, hydrophobicity, hydrogen bonding, etc., in a way previously unavailable. Such a family of ligands is the bioinorganic chemists answer to site-directed mutagenesis. Here we focus on two bioinorganic examples i.e. models for molybdoenzymes and zinc metalloproteins. 
Bioinorganic chemistry; Metalloenzyme mimics; Scorpionate ligands; Heteroscorpionate ligands; Molybdenum; Zinc 
IRIS
• Molybdenum
     Litsearch 2018
          WOS