US EPA

4849557 

Journal Article 

Spectrophotometric determination of copper(I) with molybdenum(VI) as a chromogen by molybdenum blue method 

Kumar, GVSRP; Sekhar, TC; Murty, BS 

2015 

Yes 

Journal of the Indian Chemical Society
ISSN: 0019-4522 

92 

11 

1657-1662 

WOS:000367421500007 

A simple, accurate and precise spectrophotometric method was developed by the authors for the determination copper(I) using molybdenum(vi) (ammonium molybdate solution) as a chromogen by molybdenum blue method. During the reaction between copper(I) and ammonium molybdate solution, an instantaneous, stable ink blue color (molybdenum blue) was developed, which showed a wavelength of maximum absorption at 834.8 nm. As a result of such experiments which showed remarkable sensitivity, ammonium molybdate was also used as a reagent for the spot test of copper(I). Beer's law was found to be obeyed up to 1.9798 mg of copper(I) chloride in the solution. Correlation factor was found to be 0.9746. SD and RSD were found to be well within the prescribed limits. The reagent, ammonium molybdate was also used for the photometric determination of copper(I) with good and appreciable results of accuracy. Thus the chromogen molybdenum(VI), can be used for both qualitative and quantitative determination of copper(I) in aqueous/acid media. 

Copper(I); ammonium molybdate; spectrophotometry; molybdenum blue; photometric titration