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HERO ID
4854065
Reference Type
Journal Article
Title
Substituted esters of stearic acid as potential lubricants
Author(s)
Kleinova, A; Fodran, P; Brncalova, L; Cvengros, Jan
Year
2008
Is Peer Reviewed?
1
Journal
Biomass and Bioenergy
ISSN:
0961-9534
Volume
32
Issue
4
Page Numbers
366-371
Language
English
DOI
10.1016/j.biombioe.2007.09.015
Web of Science Id
WOS:000255473600012
URL
http://
://WOS:000255473600012
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Abstract
Preparation and properties of four triesters-derivatives of 9,10-dihydroxystearic acid after the epoxidation of methyl ester of the oleic acid, opening of the formed oxirane ring in suitable medium and esterification of free hydroxyl group is discussed in the paper. Removal of the double bond from acyl of the fatty acid, increase of the molar weight and change of molecular structure resulted in increase of viscosity and oxidation stability of prepared triesters. Lubrication tests performed on a four-ball machine showed better tribological characteristics of synthesized triesters when compared with mineral additive-free base oil. (c) 2007 Elsevier Ltd. All rights reserved.
Keywords
vegetable oils; animal fats; lubricants; oleic acid; epoxidation; dihydroxystearic acid; oxidation stability; triesters; methyl esters
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