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HERO ID
4863995
Reference Type
Journal Article
Title
Measurement of Isobaric Vapor-Liquid Equilibria for Binary Systems Containing Tetrahydrofuran Using an Automatic Apparatus
Author(s)
Matsuda, H; Kamihama, N; Kurihara, K; Tochigi, K; Yokoyama, K
Year
2011
Is Peer Reviewed?
1
Journal
Journal of Chemical Engineering of Japan
ISSN:
0021-9592
Publisher
SOC CHEMICAL ENG JAPAN
Location
BUNKYO KU TOKYO
Volume
44
Issue
3
Page Numbers
131-139
Language
English
DOI
10.1252/jcej.10we162
Web of Science Id
WOS:000290947900001
Abstract
Isobaric vapor-liquid equilibria (VLE) were measured for four binary systems containing tetrahydrofuran (THF): THF + water, and three different mixtures of THF + n-alkane (n-pentane, n-hexane, and n-heptane). Measurements were conducted at pressures in the range 40.0-101.3 kPa using a simple, automatic apparatus developed in our laboratory. From the experimental VLE data it was confirmed that the THF + water and THF + n-hexane systems formed minimum-boiling-point azeotropes, whereas the THF + n-pentane and THF + n-heptane systems were non-azeotropic mixtures. Non-random two-liquid (NRTL) parameters were also determined on the basis of the experimental VLE data.
Keywords
Experimental; Vapor-Liquid Equilibria; Azeotrope; NRTL Parameter; Azeotropic Distillation
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