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4866542 
Journal Article 
First-stage ignition delay in the negative temperature coefficient behavior: Experiment and simulation 
Zhang, P; Ji, W; He, T; He, Xin; Wang, Zhi; Yang, Bin; Law, CK 
2016 
Yes 
Combustion and Flame
ISSN: 0010-2180 
167 
14-23 
WOS:000374802900002 
The existence of the first-stage ignition delay (FID) negative temperature coefficient (NTC) behavior was confirmed by rapid compression machine experiments using iso-octane and methyl-cyclohexane. The first-stage NTC behavior of iso-octane is observed in the temperature range 757-782 K under 20 bar and phi=1. For methyl-cyclohexane, the observed first-stage NTC temperature range is 750-785 K under 15 bar and phi=0.5. In further iso-octane experiments, the FID is found to be sensitive to the O-2 concentration and insensitive to the dilution gas and fuel concentrations. The effects of the FID and its NTC behavior on the total ignition delay NTC were analyzed using a detailed n-heptane mechanism. The contributions to the total ignition delay NTC from the reduced second-stage initial temperature, pressure, and less reactive species pool, together with the NTC of FID were discussed quantitatively. For the first-stage NTC behavior, five competing reactions were identified as being important based on sensitivity analysis, reaction pathway analysis, and simplified mechanism method. They are the backward reaction of second O-2 addition, RO2 double left right arrow alkene+HO2, QOOH double left right arrow cyclic-ether+OH, QOOH double left right arrow alkene+HO2, and the beta scission reaction of the alkyl radical. Their competition with the low-temperature branching channel finally leads to the first-stage NTC behavior. (C) 2016 The Combustion Institute. Published by Elsevier Inc. All rights reserved. 
First-stage ignition; Negative temperature coefficient; Rapid compression machine; Low-temperature mechanism