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HERO ID
4882264
Reference Type
Journal Article
Title
Dielectric constants, molar polarizations, and refractive indices for 2-butoxyethanol plus hexane and plus heptane at 30 degrees and 40 degrees C
Author(s)
Sastry, NV; Raj, MM
Year
1996
Is Peer Reviewed?
Yes
Journal
Journal of Solution Chemistry
ISSN:
0095-9782
EISSN:
1572-8927
Publisher
Kluwer Academic/Plenum Publishers
Volume
25
Issue
11
Page Numbers
1137-1149
Language
English
DOI
10.1007/BF00972928
Web of Science Id
WOS:A1996VZ47400009
Abstract
Static dielectric constants and refractive indices of 2-butoxyethanol-n-hexane and-n-heptane mixtures were measured at 30 and 40 degrees C and the various dielectric excess functions viz. dielectric constants, molar polarizations, and orientation polarizations were evaluated. The excess dielectric constants and molar polarizations were found to be unsymmetrical and negative over the entire range of mole fraction. The trend in the variation of excess orientation polarization has shown three characteristic regions. The excess functions were smoothed through a variable degree polynomial. The results show the dominance of dipole-dipole interactions in the butoxyethanol deficient regions and weak specific interactions with unlike alkane molecules at higher butoxyethanol mole fractions.
Keywords
static dielectric constants; refractive indices; molar polarizations; orientation polarizations; dipole-dipole interactions
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