ALTERNATIVE HYDROCARBON SOLVENTS FOR COTTONSEED EXTRACTION

Wan, PJ; Pakarinen, DR; Hron, RJ; Richard, OL; Conkerton, EJ

HERO ID

4882380

Reference Type

Journal Article

Year

1995

Language

English

HERO ID 4882380
In Press No
Year 1995
Title ALTERNATIVE HYDROCARBON SOLVENTS FOR COTTONSEED EXTRACTION
Authors Wan, PJ; Pakarinen, DR; Hron, RJ; Richard, OL; Conkerton, EJ
Journal Journal of the American Oil Chemists' Society
Volume 72
Issue 6
Page Numbers 653-659
Abstract Hexane has been used for decades to extract edible oil from cottonseed. However, due to increased regulations affecting hexane because of the 1990 Clean Air Act and potential health risks, the oil-extraction industry urgently needs alternative hydrocarbon solvents to replace hexane. Five solvents, n-heptane, isohexane, neohexane, cyclohexane, and cylopentane, were compared with commercial hexane using a bench-scale extractor. The extractions were done with a solvent to cottonseed flake ratio of 5.5 to 1 (w/w) and a miscella recycle flow rate of 36 mL/min/sq cm (9 gal/min/sq ft) at a temperature of 10 to 45 degrees C below the boiling point of the solvent. After a 10-min single-stage extraction, commercial hexane removed 100% of the oil from the flakes at 55 degrees C; heptane extracted 100% at 75 degrees C and 95.9% at 55 degrees C; isohexane extracted 93.1% at 45 degrees C; while cyclopentane, cyclohexane, and neohexane removed 93.3, 89.4, and 89.6% at 35, 55, and 35 degrees C, respectively. Each solvent removed gossypol from cottonseed flakes at a different rate, with cyclopentane being most and neohexane least effective. Based on the bench-scale extraction results and the availability of these candidate solvents, heptane and isohexane are the alternative hydrocarbon solvents most likely to replace hexane.
Doi 10.1007/BF02635650
Wosid WOS:A1995RC94400006
Is Certified Translation No
Dupe Override No
Comments Scopus URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-0009951270&doi=10.1007%2fBF02635650&partnerID=40&md5=7cf6843565aa4bf81e3b36a549998c1e
Is Public Yes
Language Text English
Keyword ALTERNATIVE SOLVENTS; COTTONSEED; CYCLOHEXANE; CYCLOPENTANE; EXTRACTION; EXTRACTION EFFICIENCY AND RATE; HEPTANE; HEXANE; HYDROCARBON SOLVENTS; ISOHEXANE; MISCELLA; MISCELLA CONCENTRATION; NEOHEXANE