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HERO ID
4883971
Reference Type
Journal Article
Title
Densities and derived thermodynamic properties for the (n-heptane plus n-octane), (n-heptane plus ethanol) and (n-octane plus ethanol) systems at high pressures
Author(s)
Abdussalam, AliA; Ivanis, GR; Radovic, IR; Kijevcanin, MLj
Year
2016
Is Peer Reviewed?
1
Journal
Journal of Chemical Thermodynamics
ISSN:
0021-9614
Volume
100
Page Numbers
89-99
DOI
10.1016/j.jct.2016.04.014
Web of Science Id
WOS:000376187200010
Abstract
This work reports densities for the pure n-heptane, n-octane and ethanol at temperatures from (288.15 to 413.15) K and at pressures up to 60 MPa. The same properties were determined for the binary mixtures n-heptane + n-octane, n-heptane + ethanol and n-octane + ethanol over the temperature range (293.15-373.15) K and at pressures ranging from (0.1 to 40) MPa. Highly precise densimeter DMA HP was used for density measurements. Experimental values of densities were fitted by the modified Tammann-Tait equation. Additionally, derived volumetric properties, e.g. excess molar volumes, isothermal compressibilities and isobaric thermal expansion coefficients were calculated. The effect of pressure and temperature on the measured and derived properties was discussed. (C) 2016 Elsevier Ltd. All rights reserved.
Keywords
High pressure density; Isothermal compressibility; Isobaric thermal expansion coefficient; Binary mixtures
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