Construction of spiro[4.5]decane via ring-closing metathesis reaction: Formal synthesis of acorone and isoacorones | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

4892631

Reference Type

Journal Article

Title

Construction of spiro[4.5]decane via ring-closing metathesis reaction: Formal synthesis of acorone and isoacorones

Author(s)

Srikrishna, A; Rao, MS

Year

2008

Is Peer Reviewed?

Journal

Indian Journal of Chemistry. Section B
ISSN: 0376-4699
EISSN: 0975-0983

Volume

Issue

Page Numbers

1423-1429

Language

English

Web of Science Id

WOS:000259485400005

Abstract

A Claisen rearrangement and RCM reaction based sequence has been developed for formal total synthesis of acorone and isoacorones starting from cyclohexane-1,4-dione. It has been further modified and avoided the protection deprotection sequence in the second strategy.

Keywords

spiro[4.5]decane; acorones; RCM reaction; Claisen rearrangement; sesquiterpenes