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HERO ID
4921153
Reference Type
Journal Article
Title
Hydrogen-bonding-mediated Dynamic Covalent Synthesis of Two Chiral Capsular Compounds
Author(s)
Xu Xiao-Na; Wang Lu; Zhao Xin; Li Zhan-Ting
Year
2011
Is Peer Reviewed?
1
Journal
Gaodeng Xuexiao Huaxue Xuebao / Chemical Journal of Chinese Universities
ISSN:
0251-0790
Volume
32
Issue
9
Page Numbers
2162-2168
Web of Science Id
WOS:000295441000028
Abstract
Two chiral two-layered capsular compounds have been synthesizied from chiral cyclohexane-1,2-diamine-derived dipodal precursors. The precursors bear both amino and aldehyde groups which are connected to two intramolecularly hydrogen bonded foldamer segments. Intramolecular hydrogen bonding facilitates the selective generation of two macrocyclic moieties by forming six imine bonds.
Keywords
Hydrogen bond; Chiral capsule molecule; Dynamic covalent chemistry; Foldamer; Imine formation
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