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5062133 
Journal Article 
Synthesis, Structure and Characterization of a 3D Chiral Carboxylate and Phosphonate Metal-organic Framework Based on 1,1 '-Biphenol Ligand 
Jiao Jing-Jing; Li Zi-Jian; Zheng Fa-Kun; Liu Bai-Zhan; Cui Yong 
2018 
Yes 
Chinese Journal of Structural Chemistry
ISSN: 0254-5861 
37 
9 
1509-1515 
WOS:000454263400018 
A novel phosphonate-based chiral metal-organic framework 1 was synthesized from C-2-symmetric 1,1'-biphenol-based ligand and structurally characterized by single-crystal and powder X-ray diffraction, Fourier-transform infrared spectra (FTIR), circular dichroism (CD) and thermogravimetric analyses (TGA). Two neighboring Mn ions are linked by two carboxylate groups and one phosphate group to form a di-manganese unit [Mn-2] and each [Mn-2] cluster in 1 is linked by five ligands, generating a 3D network with fns topology. In addition, the photoluminescence properties of 1 and H4L were investigated. 
biphenol; phosphonate; manganese; chiral metal-organic framework