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5072588 
Journal Article 
Preparation, characterization, and catalytic performance of PdPt/3DOM LaMnAl11O19 for the combustion of methane 
Xua, P; Zhang, X; Zhao, X; Yang, Jun; Hou, Z; Bai, Lu; Chang, H; Liu, Y; Deng, J; Guo, G; Dai, H; Au, CT 
2018 
1 
Applied Catalysis A: General
ISSN: 0926-860X
EISSN: 1873-3875 
562 
284-293 
WOS:000443630600031 
Three-dimensionally ordered macroporus LaMnAl11O19 (3DOM LMAO) and its supported Pd, Pd-Pt, and Pt nanoparticles were prepared using the polymethyl methacrylate-templating and polyvinyl alcohol-protected reduction methods, respectively. The 1100 degrees C-calcined 3DOM LMAO support possessed a hexaaluminate phase, and its supported noble metal samples displayed a high surface area of 26-29 m(2)/g. A Pd-Pt alloy was generated in the PdPt/3DOM LMAO samples, and the particle sizes of the noble metal nanoparticles (NPs) were 3-5 nm. The 0.97 wt% Pd/3DOM LMAO (0.97 P d/3DOM LMAO) sample possessed the highest surface adsorbed oxygen concentration and the best low-temperature reducibility, showing the highest catalytic activity (T-10% = 259 degrees C, T-50% = 308 degrees C, and T-90% = 343 degrees C at SV = 20,000 mL/(g h)) for methane combustion. The 1.14 wt% Pd2.8Pt/3DOM LMAO (1.14Pd(2.8)Pt/3DOM LMAO) sample performed the best (T-10% = 284 degrees C, T-50% = 372 degrees C, and T-90% = 456 degrees C at SV = 20,000 mL/(g h)) among the PdPt/3DOM LMAO samples. Doping of Pt to the Pd-based catalyst could improve the H2O-, CO2-, and SO2-resistant ability without significant influence on thermal stability, although 1.14Pd(2.8)Pt/3DOM LMAO was less active than 0.97 P d/3DOM LMAO for methane combustion. The ex situ X-ray photoelectron spectroscopy was used to explore the formation of active PdO species during the oxidation processes of Pd in 1.14Pd(2.8)Pt/3DOM LMAO and 0.97Pd/3DOM LaMnAl11O19 at different temperatures. 
Three-dimensionally ordered macropore; Bimetallic nanoparticle; Supported noble metal catalyst; Methane combustion; Ex situ XPS