Lead/Rare Earth-Free Green-Light-Emitting Crystal of Molecular-Based Hybrid Compound: (C5H13ClN)(2)[MnCl4] with Large Crystal Size | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

5075765

Reference Type

Journal Article

Title

Lead/Rare Earth-Free Green-Light-Emitting Crystal of Molecular-Based Hybrid Compound: (C5H13ClN)(2)[MnCl4] with Large Crystal Size

Author(s)

Cai Xing-Wei; Qiang Wei; Zhao Yu-Yuan; Li Hong; Huang Cui-Ping; Guo Yong-Chun

Year

2018

Is Peer Reviewed?

Yes

Journal

Chinese Journal of Inorganic Chemistry / Wu Ji Hua Xue Xue Bao
ISSN: 1001-4861

Publisher

CHINESE CHEMICAL SOC

Location

BEIJING

Volume

Issue

Page Numbers

283-288

DOI

10.11862/CJIC.2018.068

Web of Science Id

WOS:000429758300009

Abstract

Reaction of MnCl2 and 2-dimethylaminoisopropyl chloride hydrochloride afforded one novel molecular based material, (C5H13ClN)(2)[MnCl4] (1). And it is interesting to note that 1 exhibits intense greenish fluorescent emission (520 nm) at room temperature and relatively high thermal stability (stable up to 450 K). Moreover, structure and spectra analyses reveal that its excellent optical property can be attributed to the T-4(1) (G)->(6)A(1) electronic transition of Me in [MnX4](2-) tetrahedron. CCDC: 1570589.

Keywords

organic-inorganic hybrid; crystal structure; luminescence