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HERO ID
5168102
Reference Type
Journal Article
Title
A facile and green synthesis of N-substituted imides
Author(s)
Kumar, PP; Devi, BR; Dubey, PK
Year
2013
Is Peer Reviewed?
1
Journal
Indian Journal of Chemistry. Section B
ISSN:
0376-4699
EISSN:
0975-0983
Volume
52
Issue
8
Page Numbers
1166-1171
Language
English
Web of Science Id
WOS:000323592100006
URL
http://
://CCC:000323592100006http://www.csir.res.in
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Abstract
Anhydrides 1, 6 and 10 have been reacted, independently, with aromatic primary amines 2 in solid phase by simple physical grinding of reactants with p-toluenesulphonic acid as a catalyst to yield corresponding open chain derivatives, monoacid monoamides 3, 7 and 11 respectively. The latter have each been transformed into the corresponding cyclic derivatives, i.e. imides 5, 9 and 13 respectively in solid phase by simple physical grinding of each with K2CO3, alkylating agent and tetrabutylammoniumbromide as a catalyst with short reaction times. These cyclic imides can also be obtained by physical grinding of each of 3, 7 and 11 with dicyclohexylcarbodimide as a dehydrating agent in solid phase.
Keywords
Polymer Science; Phthalic anhydride, maleic anhydride, succinic anhydride, TBAB, DCC; aryl phthalimides, efficient
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