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HERO ID
5175973
Reference Type
Journal Article
Title
Acyl iodides in organic synthesis: IV. Reaction of acetyl iodide with carboxylic acids
Author(s)
Voronkov, MG; Belousova, LI; Trukhina, AA; Vlasova, NN
Year
2003
Is Peer Reviewed?
1
Journal
Russian Journal of Organic Chemistry
ISSN:
1070-4280
EISSN:
1608-3393
Volume
39
Issue
12
Page Numbers
1702-1705
Language
English
DOI
10.1023/b:rujo.0000019730.43667.46
Web of Science Id
WOS:000220320700002
URL
http://
://CCC:000220320700002http://www.maik.rssi.ru
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Abstract
In contrast to acyl chlorides, reactions of acetyl iodide with monocarboxylic acids follow the exchange pattern to give the corresponding acyl iodides and acetic acid. The reaction attracts interest from the preparative viewpoint as a simple and convenient route to acyl iodides. Acetyl iodide reacts with phthalic acid, yielding acetic acid and phthalic anhydride, while the reaction of acetyl iodide with oxalic acid leads to formation of acetic acid, carbon(II) oxide, and molecular iodine.
Keywords
Polymer Science
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