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HERO ID
5177800
Reference Type
Journal Article
Title
Thermal degradation products of steel protective paints
Author(s)
Henriks-Eckerman, ML; Engstrom, B; Anas, E
Year
1990
Is Peer Reviewed?
Yes
Journal
American Industrial Hygiene Association Journal
ISSN:
0002-8894
Volume
51
Issue
4
Page Numbers
241-244
Language
English
DOI
10.1202/0002-8894(1990)051<0241:TDPOSP>2.0.CO;2
Web of Science Id
WOS:A1990CX54000009
Abstract
Organic degradation and emission products from painted steel were studied in laboratory experiments. Steel plates coated with paints for the ship building industry were heated with a liquid gas flame to 350°C. Emitted products were collected by different adsorption tubes, bubbler absorbers, and filters, for identification by gas chromatography, liquid chromatography, and mass spectrometry. The main degradation products typically originated from the binders in the paints, i.e., bisphenol-A from epoxies, phthalic anhydride from alkyds, butyraldehyde from polyvinylbutyral. Small molecular aldehydes, acids, and solvents were also detected. For sampling on-site an XAD-2 tube with a pre-connected glass fiber filter and a chemosorbent tube for aldehydes is recommended.
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