Auto-catalysis and effects of the solvent in the reaction of phthalic anhydride with aniline derivatives | Health & Environmental Research Online (HERO)

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HERO ID

5179503

Reference Type

Journal Article

Title

Auto-catalysis and effects of the solvent in the reaction of phthalic anhydride with aniline derivatives

Author(s)

Kalninsh, KK

Year

1988

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Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

1768-1773

Language

English

DOI

10.1007/BF00962484

Web of Science Id

WOS:A1988AD10500006

URL

http://://WOS:A1988AD10500006
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Abstract

1. A new method of analysis of autocatalytic reactions was developed which permits determining the rate constants of noncatalytic and catalytic reaction pathways with the data from one kinetic curve. 2. The reverse reaction of acylation has an autocatalytic character. 3. In comparison to CHCl3, in CH3CN, all of the rate constants increase by 2-4 times, and the noncatalytic reaction pathways are more sensitive to the nature of the solvent. © 1989 Plenum Publishing Corporation.